高 瑞

      特聘研究员,博士生导师

      办公室:化学楼502

      邮箱:gaorui@imu.edu.cn


 

教育背景

2003-2007内蒙古大学大学化学化工学院读本科,获工学学士学位

2008-2014:中国科学院大学山西煤炭化学研究所硕博连读,获理学博士学位

工作经历

2014-2017:北京大学,博士后

2014-2017:中科合成油技术有限公,研究助理

2017-至今:2022世界杯预选赛买球,研究员

研究领域

1.      CO2CH4催化转化利用的催化剂(M1@2D)开发及反应机理;

2.      甘油(Pt/WOx)和丁二烯(NiCu合金,MoxC)选择性加氢催化剂及反应机理;

3.      金属化合物材料的HEROERORR反应性能;

4.      合成氨催化剂的理论与实验研究;

5.      费托合成催化剂Fe基催化剂体系的结构及费托反应机理。

教学

主讲2022世界杯预选赛买球大二《色谱分析》、大三《结构化学》、大三《材料结构与性能》、大四《催化材料导论》、研究生《计算机化学

荣誉与奖励

1.        内蒙杰青(2021年)

2.        第九批草原英才工程人才(2019年)

3.        自治区新世纪“321人才工程第二层次(2019年)

研究项目

1.        国家自然科学基金,面上项目,2022.01-2025.1260万元,在研,主持

2.        国家自然科学基金,地区项目,2020.01-2023.1240万元,在研,主持

3.        国家自然科学基金,青年项目,2019.01-2021.1227.5万元,在研,主持

4.        内蒙古自治区自然科学基金,杰出青年培育基金项目,2021.01-2023.1230万元,在研,主持

5.        内蒙古大学“骏马计划”人才项目B1岗,300万,在研,主持

6.        内蒙古引进高层次人才科研支持项目,25万,在研,主持

7.        “草原英才”项目,10万,在研,主持

代表性成果

(1)     Baocang Liu, Yan Cheng, Bo Cao, Minghao Hu, Peng Jing, Rui Gao*, Yaping Du*, Jun Zhang*, Jinghai Liu, Hybrid heterojunction of molybdenum disulfide/single cobalt atoms anchored nitrogen, sulfur-doped carbon nanotube/cobalt disulfide with multiple active sites for highly efficient hydrogen evolution. Appl. Catal. B: Environ. 2021, 298, 120630.

(2)     Yan Cheng#, Juhui Gong#, Bo Cao, Xuan Xu, Peng Jing, Baocang Liu,* Rui Gao*, Jun Zhang*, ACS Catal. 2021, 11, 39583974.

(3)     Lili Huo, Xi Han, Luyao Zhang, Liu Baocang*, Rui Gao*, Chun-Jiang Jia*, Jun Zhang*, Appl. Catal. B: Environ. 2021, 294, 120254.

(4)     Lili Lin#, Qiaolin Yu#, Mi Peng#, Aowen Li, Siyu Yao, Shuheng Tian, Xi Liu, Ang Li, Zheng Jiang, Rui Gao*, Xiaodong Han, Yong-wang Li, Xiao-dong Wen, Wu Zhou*, and Ding Ma*, Atomically dispersed Ni/α-MoC catalyst for hydrogen production from methanol/water. J. Am. Chem. Soc. 2021, 143, 309-317.

(5)     Yuanjun Chen#, Rui Gao#, Shufang Ji, Haijing Li, Kun Tang, Peng Jiang, Haibo Hu, Zedong Zhang, Haigang Hao, Qingyun Qu, Xiao Liang, Wenxing Chen, Juncai Dong, Dingsheng Wang*, and Yadong Li, Atomic-Level Modulation of Electronic Density at Cobalt Single-Atom Sites Derived from Metal–Organic Frameworks: Enhanced Oxygen Reduction Performance. Angew. Chem. Int. Ed. 2021, 133, 3249-3258.

(6)     Bo Liu, Zhe Yan, Tong Xu, Junzhong Wang, Chunping Li, Rui Gao*, Jie Bai*, Promoting electron transfer of surface oxygen vacancies in Pd/CeO2-RE via doping engineering for enhancing catalytic activity in Suzuki coupling reaction. J. Catal. 2021, 399, 15–23.

(7)     Bo Cao, Minghao Hu, Yan Cheng, Peng Jing, Baocang Liu*, Bo Zhou, Xi Wang, Rui Gao*, Xiaolei Sun, Yaping Du*, Jun Zhang*, Tailoring the d-band center of N-doped carbon nanotube arrays with Co4N nanoparticles and single-atom Co for a superior hydrogen evolution reaction. NPG Asia Mater. 2021, 13, 1.

(8)     Huan Li, Minghao Hu, Bo Cao, Peng Jing, Baocang Liu*, Rui Gao*, Jun Zhang*, Xiaomeng Shi, Yaping Du*, Multi-Elemental Electronic Coupling for Enhanced Hydrogen Generation. Small 2021, 2006617.

(9)     Punian Yin#, Huizhu Cai#, Xiao Zhang, Bingbing Chen, Yang Liu, Rui Gao*, Chuan Shi, α-MoC1-x nanorods as an efficient hydrogen evolution reaction electrocatalyst. New J. Chem. 2021, 45, 10396-10401.

(10) Xiao Zhang#, Mengtao Zhang#, Yuchen Deng#, Mingquan Xu#, Luca Artiglia, Wen Wen, Rui Gao, Bingbing Chen, Siyu Yao, Xiaochen Zhang, Mi Peng, Jie Yan, Aowen Li, Zheng Jiang, Xingyu Gao, Sufeng Cao, Ce Yang, A. Jeremy Kropf, Jinan Shi, Jinglin Xie, Mingshu Bi, Jeroen A. van Bokhoven, Yong-Wang Li, Xiaodong Wen, Maria Flytzani-Stephanopoulos, Chuan Shi*, Wu Zhou*, Ding Ma*, A stable low-temperature H2-production catalyst by crowding Pt on α-MoC. Nature 2021, 589, 396-401.

(11) Huan Li#, Minghao Hu#, Luyao Zhang, Lili Huo, Peng Jing, Liu Baocang*, Rui Gao*, Jun Zhang* and Liu Bin*, Hybridization of Bimetallic Molybdenum-Tungsten Carbide with Nitrogen-Doped Carbon: A Rational Design of Super Active Porous Composite Nanowires with Tailored Electronic Structure for Boosting Hydrogen Evolution Catalysis. Adv. Funct. Mater. 2020, 200319.

(12) Mao Sun, Rui-Ting Gao, Xianhu Liu, Rui Gao*, Lei Wang*, Manganese-based oxygen evolution catalysts boosting stable solar-driven water splitting: MnSe as an intermetallic phase. J. Mater. Chem. A, 2020, 8, 25298–25305.

(13) Baocang Liu, Bo Cao, Yan Cheng, Peng Jing*, Jian Zhao, Rui Gao*, Anthony. O’Mullane, Huaiyong Zhu, Kaiqiang Liu, Xiaolei Sun, Yaping Du*, and Jun Zhang*, Ultrafine CoP/Co2P Nanorods Encapsulated in Janus/Twins Type Honeycomb 3D Porous Nitrogen Doped Carbon Nanosheets for Efficient Hydrogen Evolution. iScience 2020, 23, 101264.

(14) Xin Zhang, Rongbo Zhao, Na Zhang, Yiguo Su, Zhiliang Liu, Rui Gao*, Chun Fang Du*, Insight to unprecedented catalytic activity of double-nitrogen defective metal-free catalyst: Key role of coal gangue. Appl. Catal. B: Environ. 2020, 263, 118316.

(15) Lili Lin#, Siyu Yao#, Rui Gao#, Xuan Liang, Qiaolin Yu, Yuchen Deng, Jinjia Liu, Mi Peng, Zheng Jiang, Siwei Li, Yongwang Li, Xiaodong Wen*, Wu Zhou*, Ding Ma*, A highly CO-resistant Pt catalyst for chemoselective hydrogenation. Nature nano. 2019, 14, 354-361.

(16) Bo Cao, Yan Cheng, Minghao Hu, Peng Jing, Zhixue Ma, Baocang Liu*, Rui Gao*, Jun Zhang*, Effcient and Durable 3D Self-Supported Nitrogen-Doped Carbon-Coupled Nickel/Cobalt Phosphide Electrodes: Stoichiometric Ratio Regulated Phase- and MorphologyDependent Overall Water Splitting Performance. Adv. Funct. Mater. 2019, 1906316.

(17) Rui Gao#, xingchen Liu#, Zhi Cao#, xing-Wu Liu, Kuan Lu, Ding Ma, Yong Yang, Yong-Wang Li, Roald Hoffmann, Xiao-Dong Wen, Carbon Permeation: The Prerequisite Elementary Step in lron-Catalyzed Fischer-Tropsch Synthesis. Catalysis Letters 2019, 149, 645-664.

(18) Baocang Liu, Huan Li, Bo Cao, Jianing Jiang, Rui Gao* and Jun Zhang*, Few Layered N-doped Carbon Encapsulated Ultrafine MoP Nanocrystals/MoP Clusters Hybrids on Carbon Cloth: A Ultra-high Active and Durable 3D Self-supported Integrated Electrode for Hydrogen Evolution Reaction in a Wide pH Range. Adv. Funct. Mater. 2018, 1801527.

(19) Guangran Xu, Rui Si, Jiayin Liu, Luyao Zhang, Xia Gong, Rui Gao*, Baocang Liu* and Jun Zhang*, Directed Self-Assembly Pathways of Three-dimensional Pt/Pd Nanocrystal Superlattices Electrocatalysts for Enhanced Methanol Oxidation Reaction. J. Mater. Chem. A 2018, 6, 12759-12767.

(20) Yuchen Deng#, Rui Gao#, Lili Lin#, Tong Liu, Xiao-Dong Wen, Shuai Wang*, Ding Ma*, Solvent Tunes the Selectivity of Hydrogenation Reaction over α‑MoC Catalyst. J. Am. Chem. Soc. 2018, 140, 14481-14489.

(21) Wa Gao#, Rui Gao#, Yufei Zhao#, Mi Peng, Chuqiao Song, Mengzhu Li, Siwei Li, Jinjia Liu, Weizhen Li, Yuchen Deng, Mengtao Zhang, Jinglin Xie, Gang Hu, Zhaosheng Zhang, Run Long, Xiao-Dong Wen*, Ding Ma*, Photo-Driven Syngas Conversion to Lower Olefins over Oxygen-Decorated Fe5C2 Catalyst. Chem 2018, 4, 1-12.

(22) Guangbo Chen#, Rui Gao#, Yufei Zhao#, Zhenhua Li, Geoffrey I.N. Waterhouse, Run Shi, Jiaqing Zhao, Mengtao Zhang, Lu Shang, Guiyang Sheng, Xiangping Zhang, Xiaodong Wen, Li-Zhu Wu, Chen-Ho Tung, Tierui Zhang, Photothermal CO2 Hydrogenation to Hydrocarbons using CoFeAl–Layered Double Hydroxides Nanosheets-Derived Catalysts. Adv. Mater. 2018, 30, 1704663.

(23) Haigang Hao#, Pengfei Lian#, Juhui Gong, Rui Gao*, Theoretical Study on the Hydrogenation Mechanisms of Model Compounds of Heavy Oil in a Plasma-Driven Catalytic System. Catalysts 2018, 8, 381.

(24) Haigang Hao§, Tong Chang§, Linxia Cui, Ruiqing Sun, Rui Gao*, Theoretical Study on the Mechanism of Hydrogen Donation and Transfer for Hydrogen-Donor Solvents during Direct Coal Liquefaction. Catalysts 2018, 8, 648.

(25) Lili Lin#, Wu Zhou#, Rui Gao#, Siyu Yao, Xiao Zhang, Wenqian Xu, Shijian Zheng, Zheng Jiang, Yong Wang Li, Chuan Shi, Xiao-Dong Wen, Ding Ma, Base-free low temperature hydrogen production from methanol/water over Pt/α-MoC catalysts. Nature 2017, 544, 80-83.

(26) Siyu Yao§, Xiao Zhang§, Wu Zhou§, Rui Gao, Wenqian Xu, Yifan Ye, Lili Lin, Xiaodong Wen, Ping Liu, Ethan Crumlin, Jinghua Guo, Zhijun Zuo, Weizhen Li, Jinglin Xie, Christopher J. Kiely, Li Lu, Lin Gu, Chuan Shi, José A. Rodriguez, Ding Ma, Atomic-layered Au clusters on α-MoC for the low temperature water gas shift reaction. Science 2017, 357, 389-393.